Here's the low down on any type of "horn" (NOT antler) material. It is nothing more then compressed hair (keratin), and anything that can happen to your girlfriend's or wife's hair on "a bad hair day" can happen to this type of handle material. Personally I classify horn as something best left to experienced knifemakers.
Anyway. On to your issue. I am totally against using water, boiling, or any other type of "moisture" treatment on horn handle scales. Why? Because in the end, you will only exacerbate the problem(s).
My preferred method is to grind the warp out, assuming there is enough material thickness to allow it. Now, when I say "grind"..... I mean SLOW AND EASY! Little amounts at a time. If you allow the horn to become warm to the touch while grinding out a warp..... you'll never get it out. The warp will just keep going until you run out of material. Slow speed on the grinder, NEW/sharp belts, and grind just a bit, then allow the material to cool. Patience it key.... you try to rush it too much, and everything your doing will backfire on you. Oh, and DO NOT dip it in water if it get warm to the touch!
All of that might seem like a royal pain, but it's what you sign up for when you choose to use horn for handle material. It's not a simple or easy material to use/work with. You also need to be fully aware that the material, once on a completed knife WILL move. Meaning it will shrink and expand with environment changes. How much it moves, depends on many factors, but rest assured it will.