I don’t go for as long as Ed, but I am also a proponent of more than one tempering cycle. I started out repeating cycles because one thing I learned a long time ago is that there are no set tempering numbers to give you specific HRC numbers, each piece of steel and each heat treatment is different. People still contact me wanting to know what temperature they should temper their steel at to get a certain Rockwell number, and my standard reply is- sorry I’m not in your shop and it’s just not that simple. So, I started doing shorter tempers at lower temperatures followed by Rockwell tests before bumping the temperature up and walking it into the exact HRC I wanted.
After the first two notebooks of HRC numbers, I started to notice a pattern in the data. The groupings of HRC number deviation got tighter with every temper. As Ed also noticed, at 3 cycles the grouping was a tight as it could get. What I mean is this- my first series of numbers may have had a deviation of as much as one point Rockwell between them, the next series was, of course, lower but the deviation tightened to perhaps .5 HRC and on the third there was almost no deviation at all. I didn’t get the same flattening of the numbers with much longer single tempers.
I may go out to 3 or 4 hours total to carefully get the exact HRC numbers I want, but my ideal would be to have the steel behave enough not to go that long. But it is also worth noting that I temper in salts, which almost eliminates the time spent bringing the steel up to temp in an oven. I quench between tempers, to get right to the HRC testing, but since it doesn’t really hurt anything it also give me some peace of mind about arresting some precipitation processes.
Tempering is all about sub-microscopic, like atomic lattice level, movement of carbon atoms, allowing the iron matrix to “relax” a little. At these low temperatures that takes time, like an hour or two, vs a second or two. Eventually these carbon atoms will gather up enough to create tempering carbides, once again too small to see with a light microscope. Where these carbides decide to gather can have differing effects and so you get these little curve balls thrown at you like the topic of this thread.